Photovoltaics are best known as a method for generating solar power by using solar cells packaged in photovoltaic modules, often electrically connected in multiples as solar photovoltaic arrays to convert energy from the sun into electricity. To explain the photovoltaic solar panel more simply, photons from sunlight knock electrons into a higher state of energy, creating electricity.

The first practical application of photovoltaics was to power orbiting satellites and other spacecraft, but today the majority of photovoltaic modules are used for grid connected power generation. In this case an inverter is required to convert the DC to AC.

Building-integrated photovoltaics (BIPV) are increasingly incorporated into new domestic and industrial buildings as a principal or ancillary source of electrical power, and are one of the fastest growing segments of the photovoltaic industry. Typically, an array is incorporated into the roof or walls of a building, and roof tiles with integrated PV cells can now be purchased. Arrays can also be retrofitted into existing buildings; in this case they are usually fitted on top of the existing roof structure. Alternatively, an array can be located separately from the building but connected by cable to supply power for the building.

Where a building is at a considerable distance from the public electricity supply (or grid) - in remote or mountainous areas – PV may be the preferred possibility for generating electricity, or PV may be used together with wind, diesel generators and/or hydroelectric power. In such off-grid circumstances batteries are usually used to store the electric power.